5 edition of Cluster chemistry found in the catalog.
Includes bibliographical references and index.
|LC Classifications||QD921 .G65 1993|
|The Physical Object|
|Pagination||viii, 302 p. :|
|Number of Pages||302|
|ISBN 10||3540564705, 0387564705|
|LC Control Number||93012644|
In chemistry, a cluster is an ensemble of bound atoms intermediate in size between a molecule and a bulk rs exist of diverse stoichiometries and nuclearities. For example, carbon and boron atoms form fullerene and borane clusters, respectively. Transition metals and main group elements form especially robust clusters. Metal cluster chemistry has a great impact on the researchers working on organic, coordination, and solid-state chemistry, catalysis, physics, and materials science. This title includes coverage of different aspects of cluster chemistry, ranging from synthesis, structure determination, and .
System Upgrade on Tue, May 19th, at 2am (ET) During this period, E-commerce and registration of new users may not be available for up to 12 hours. This volume on iron-sulfur proteins includes chapters that describe the initial discovery of iron-sulfur proteins in the s to elucidation of the roles of iron sulfur clusters as prosthetic groups of enzymes, such as the citric acid cycle enzyme, aconitase, and numerous other proteins, ranging from nitrogenase to DNA repair proteins. The capacity of iron sulfur clusters to accept and.
Sulfur-based ligands are versatile donors that play important roles in a wide array of subdisciplines of inorganic chemistry including organometallic chemistry, bioinorganic chemistry, and cluster science. Despite the breadth of compounds containing sulfur-based ligands, those containing the simplest mercapt. Clusters occupy the middle ground between molecules and bulk solids. ‘It’s inorganic chemistry in a very fundamental sense,’ explains Stefanie research group, at the University.
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This book provides a timely overview of the whole area of clusters-both metals and non-metals. It is modestly claimed to be an introduction to the area, but in reality is far more than that. Overview, yes, but in no way superficial, as a review of the contents indicate.
The first chapter is a review-length survey of cluster chemistry (71 pp.). The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book.
About this book. Metal cluster chemistry is at the cutting edge between molecular and solid-state chemistry and has therefore had a great impact on the researchers working on organic, coordination, and solid-state chemistry, catalysis, physics, and materials science. The development of new sophisticated synthetic techniques has led to enormous.
Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements.
Main features of the. cluster chemistry, and outline the factors contributing to the stability, Cluster chemistry book and reactivity of clusters.
The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding.
All chapters within this review volume have been contributed Cluster chemistry book experts in chemistry, physics, and material sciences based at the University of Leuven, Belgium.
This book is aimed at professionals and students working in cluster science. Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties.
This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity 4/5(3). Metal Chalcogenide Cluster Chemistry. Ian Dance. School of Chemistry, University of New South Wales, Kensington, Australia.
Search for more papers by this author. Book Editor(s): Kenneth D. Karlin. Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland. Clusters of atoms and molecules • multiples of a simple subunit, e.g. C n, Ar n, or (H 2O) n • The cluster size n can vary and determines the properties • Small clusters have (nearly) all atoms on the surface Number of atoms Surface atoms radius [nm] 2 3 10 10 4 10 5 10 6 10 7 10 8 10 2 10 10 2 10 3 10 5 10 4 „micro.
clusters and polynuclear compounds, according to the extended definition given at the beginning of the introduction. Clusters of the p-block Elements Clusters of p-block Elements in a Ligand Shell: Boron Hydrides Boron hydrides display a very rich chemistry which has been extensively studied since the pioneering Stock’s work in Metal cluster chemistry is at the cutting edge between molecular and solid-state chemistry and has therefore had a great impact on the researchers working on organic, coordination, and solid-state chemistry, catalysis, physics, and materials science.
The development of new sophisticated synthetic techniques has led to enormous progress in the synthesis of this diverse class of compounds. This book deals with transition metal clusters that are prim arily decorated with carbonyl ligands. However, other types of clusters are stabilised by different ligands including borane (hydroboron) clusters that from an historical perspective laid the foundations of cluster science, and Fe4S4 based clusters ubiquitous in biological electron.
cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs.
It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding Cited by: Brand new Book. Cluster chemistry is one of the recent, exciting areas ofInorganic Chemistry.
The occurence of molecular clusters,like fullerene C60, constitutes a fundamental feature midwaybetween the chemistry of isolated chemical compounds andthat of the features of the Cluster Chemistry of both main groupand transition metal. In chemistry, an atom cluster (or simply cluster) is an ensemble of bound atoms or molecules that is intermediate in size between a simple molecule and a nanoparticle; that is, up to a few nanometers (nm) in diameter.
The term microcluster may be used for ensembles with up to couple dozen atoms. Clusters with a definite number and type of atoms in a specific arrangement are often considered a.
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Discover the best Cluster Chemistry books and audiobooks. Learn from Cluster Chemistry experts like Frontiers and Kenneth J. Klabunde. Read Cluster Chemistry books like tmp8F1A and Free Atoms, Clusters, and Nanoscale Particles for free with a free day trial. ISBN: OCLC Number: Description: xvi, pages: illustrations ; 24 cm.
Contents: A survey of cluster chemistry --Closed-shell electronic requirements for cluster compounds --Introduction to tensor surface harmonic theory --Clusters where radial bonding predominates --Clusters where or and interactions are important.
M.N. Sokolov, V.P. Fedin, in Comprehensive Inorganic Chemistry II (Second Edition), Introduction. This chapter is devoted to inorganic cluster compounds of transition elements. The term ‘cluster’ is used in the sense provided by Cotton 1 and denotes a complex containing three or more metal atoms held together at least in part by metal–metal bonds.
2 The question of metal. xvi, pages: 24 cm Includes bibliographical references and index A survey of cluster chemistry -- Closed-shell electronic requirements for cluster compounds -- Introduction to tensor surface harmonic theory -- Clusters where radial bonding predominates -- Clusters where or and interactions are important -- Skeletal rearrangements in clusters -- Condensed and high-nuclearity cluster.
Andrei Palii, Boris Tsukerblat, in Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, 1 Introduction. Magnetic molecular clusters, that is, molecular assemblies consisting of a finite numbers of exchange coupled ions, represent the class of the so-called zero dimensional magnets.
1–10 These systems are of current interest in many areas of research and.Supramolecular & Cluster Chemistry; Supramolecular & Cluster Chemistry: high nuclearity complexes. We have a general interest in the synthesis of high nuclearity clusters for numerous applications. We have developed many synthetic routes to obtain a variety of high nuclearity clusters of the 3d metals V to Cu, with the largest till date being a.Cluster - Cluster - Chemical properties: The chemical properties of clusters are a combination of the properties of bulk and molecular matter.
Several kinds of clusters, particularly those of the metallic variety, induce certain molecules to dissociate. For example, hydrogen molecules, H2, spontaneously break into two hydrogen atoms when they attach themselves to a cluster of iron atoms.